Numerical investigation of the plasma chemical pyrolysis of methane
| Authors: Tyulkov K.V., Borovik I.N., Bindiman A.P., Mukambetov R.Ya., Rebrov S.G., Yanovskiy L.S. | Published: 18.03.2026 |
| Published in issue: #3(792)/2026 | |
| Category: Mechanical Engineering and Machine Science | Chapter: Technology and Equipment for Mechanical and Physico-Technical Processing | |
| Keywords: electric arc plasma torch, pyrolysis of methane, rate of chemical reaction |
Currently, a lot of attention from researchers around the world is being paid to the problem of obtaining cheap hydrogen fuel for power plants from various raw materials. The cheapest way to produce hydrogen from hydrocarbon raw materials is plasma chemical pyrolysis. The article is devoted to the problem of modeling the workflow in a plant for producing hydrogen from methane by its conversion during plasmochemical pyrolysis. The proposed mathematical model for describing the process of methane pyrolysis has been developed taking into account soot formation. The pyrolysis process and the flow of pyrolysis products in the reactor are modeled. The calculation results are compared with the experimental data obtained on the chemical composition of pyrolysis products. The factors influencing the increase in the yield of useful products have been identified. The simulation has established the value of the reduced power equal to 7.8 kWh/kg, which ensures the maximum yield of acetylene in pyrolysis products and close to the maximum yield of hydrogen. Obtaining the maximum possible hydrogen yield in the simulated installation will require a 3-times increase in the reduced power (up to 21.8 kWh/kg), which is economically impractical.
EDN: ADZWNG, https://elibrary/adzwng
References
[1] Bilera I.V., Lebedev Yu.A., Titov A.Yu. et al. Modeling of acetylene formation from methane in a plasma jet. High Energy Chem., 2024, vol. 58, no. 3, pp. 332–342, doi: https://doi.org/10.1134/S0018143924700127
[2] Rebrov S.G., Koshlakov V.V., Golikov A.N. et al. Plasma pyrolysis of methane using a DC plasma torch. Plasma Phys. Rep., 2025, vol. 50, no. 12, pp. 1599–1603, doi: https://doi.org/10.1134/S1063780X24602141
[3] Hua F., Cheng Y., Cheng Y. Numerical study of methane to acetylene process in novel thermal plasma array reactor. Chem. Eng. J. Adv., 2022, vol. 11, art. 100309, doi: https://doi.org/10.1016/j.ceja.2022.100309
[4] Heijkers S., Aghaei M., Bogaerts A. Plasma-based CH4 conversion into higher hydrocarbons and H2: modeling to reveal the reaction mechanisms of different plasma sources. J. Phys. Chem. C, 2020, vol. 124, no. 13, pp. 7016–7030, doi: https://doi.org/10.1021/acs.jpcc.0c00082
[5] Fulcheri L., Dames E., Rohani V. Plasma-based conversion of methane into hydrogen and carbon black. Curr. Opin. Green Sustain Chem., 2024, vol. 50, art. 100973, doi: https://doi.org/10.1016/j.cogsc.2024.100973
[6] Ali Z., Song H., Trieu Nguyen U.N. et al. Hydrogen and solid carbon production via methane pyrolysis in a rotating gliding arc plasma reactor. ChemSusChem, 2025, vol. 18, no. 7, art. e202401602, doi: https://doi.org/10.1002/cssc.202401602
[7] Cheng Y., Li T., Rehmet C. et al. Detailed kinetic modeling of chemical quenching processes of acetylene-rich gas at high temperature. Chem. Eng. J., 2017, vol. 315, pp. 324–334, doi: https://doi.org/10.1016/j.cej.2017.01.040
[8] Daghagheleh O., Schenk J., Zarl M.A. et al. Feasibility of a plasma furnace for methane pyrolysis: hydrogen and carbon production. Energies, 2024, vol. 17, no. 1, art. 167, doi: https://doi.org/10.3390/en17010167
[9] Bilera I.V., Lebedev Y.A. Plasma-chemical production of acetylene from hydrocarbons: history and current status (a review). Pet. Chem., 2022, vol. 62, no. 4, pp. 329–351, doi: https://doi.org/10.1134/S0965544122010145
[10] Wnukowski M. Methane pyrolysis with the use of plasma: review of plasma reactors and process products. Energies, 2023, vol. 16, no. 18, art. 6441, doi: https://doi.org/10.3390/en16186441
[11] Moghaddam A.L., Hejazi S., Fattahi M. et al. Methane pyrolysis for hydrogen production: navigating the path to a net zero future. Energy Environ. Sci., 2025, vol. 18, no. 6, art. 2747, doi: https://doi.org/10.1039/d4ee06191h
[12] Alhamed H., Behar O., Saxena S. et al. From methane to hydrogen: a comprehensive review to assess the efficiency and potential of turquoise hydrogen technologies. Int. J. Hydrog. Energy, 2024, vol. 68, pp. 635–662, doi: https://doi.org/10.1016/j.ijhydene.2024.04.231
[13] Dou P., Qi T., Xu S. et al. Recent advances in the application of plasma technology in hydrogen energy research. Clean Energy Sci. Technol., 2025, vol. 3, no. 2, art. 370, doi: https://doi.org/10.18686/cest370
[14] Kodryanu N.P., Ishmurzin A.A., Daudi D.I. et al. Theoretical basis and practical analysis of the technologies for the hydrogen strategy of the Russian Federation. Gazovaya promyshlennost, 2022, no. 1, pp. 56–70. (In Russ.).
[15] Miller S.A. Acetylene. Its properties, manufacture, and uses. Vol. 1. Academic Press, 1965. 800 p. (Russ. ed.: Atsetilen, ego svoystva, poluchenie i primenenie. T. 1. Leningrad, Khimiya Publ., 1969. 679 p.)
[16] Andreev D.N. Organicheskiy sintez v elektricheskikh razryadakh [Organic synthesis in electrical discharges]. Moscow, Leningrad, Izd-vo Akad. nauk SSSR Publ., 1953. 336 p. (In Russ.).
[17] Polak L.S. Kinetika i termodinamika khimicheskikh reaktsiy v nizkotemperaturnoy plazme [Kinetics and thermodynamics of chemical reactions in low-temperature plasma]. Moscow, Nauka Publ., 1965. 256 p. (In Russ.).
[18] Troshin K.Ya. Kinetic modeling of the quenching of combustion products during the synthesis of acetylene. Khimicheskaya fizika, 2019, vol. 38, no. 8, pp. 3–11, doi: https://doi.org/10.1134/S0207401X19080132 (in Russ.). (Eng. version: Russ. J. Phys. Chem. B, 2019, vol. 13, no. 4, pp. 577–584, doi: https://doi.org/10.1134/S1990793119040274)
[19] ANSYS student free student software. ansys.com: website. URL: https://www.ansys.com/academic/free-student-products (accessed: 15.11.2023).
[20] Frenklach M., Wang H., Goldenberg M. Reduced detailed mechanism for methane combustion. Energy and Power Engineering, 2012, vol. 4, no. 1, pp. 28–33, doi: http://dx.doi.org/10.4236/epe.2012.41004
[21] Gran I.R., Magnussen B.F. A numerical study of a bluff-body stabilized diffusion flame. Part 1. Influence of turbulence modeling and boundary conditions. Combust. Sci. Technol., 1996, vol. 119, no. 1–6, pp. 171–190, doi: https://doi.org/10.1080/00102209608951998
[22] Gran I.R., Magnussen B.F. A numerical study of a bluff-body stabilized diffusion flame. Part 2. Influence of combustion modeling and finite-rate chemistry. Combust. Sci. Technol., 1996, vol. 119, no. 1–6, pp. 191–217, doi: https://doi.org/10.1080/00102209608951999
[23] Pope S.B. Computationally efficient implementation of combustion chemistry using in situ adaptive tabulation. Combustion Theory and Modelling, 1997, vol. 1(1), pp. 41–63, doi: https://doi.org/10.1080/713665229
[24] Tesner P.A., Snegirova T.D., Knorre V.G. Kinetics of dispersed carbon formation. Combust. Flame, 1971, vol. 17, no. 2, pp. 253–260, doi: https://doi.org/10.1016/S0010-2180(71)80168-2
[25] Semenov N.N. Tsepnye reaktsii [Chain reactions]. Moscow, Nauka Publ., 1986. 535 p. (In Russ.).
[26] Tesner P.A. Obrazovanie ugleroda iz uglevodorodov gazovoy fazy [Formation of carbon from gas-phase hydrocarbons]. Moscow, Khimiya Publ., 1972. 136 p. (In Russ.).
[27] Magnussen B.F., Hiertager B.H. On mathematical modeling of turbulent combustion with special emphasis on soot formation and combustion. Symposium (International) on Combustion, 1977, vol. 16, no. 1, pp. 719–729, doi: https://doi.org/10.1016/S0082-0784(77)80366-4
[28] Raw M.J. Robustness of coupled algebraic multigrid for the Navier-Stokes equations. AIAA 34th Aerospace Sciences Meeting and Exhibit, Reno. 1996.
[29] Ilin V.P. Multigrid methods of incomplete factorization in Krylov subspaces. Zapiski nauchnykh seminarov POMI, 2022, vol. 514, pp. 61–76. (In Russ.). (Eng. version: J. Math. Sci., 2023, vol. 272, no. 4, pp. 523–532, doi: https://doi.org/10.1007/s10958-023-06446-6)